It is well known that the water absorption in polyamide leads to a large reduction in the mechanical properties of the polymer, which is induced by the plasticization of the amorphous phase. However, predicting such a loss in a marine environment is not straightforward, especially when thick samples are considered. This study presents a modeling study of the water absorption in polyamide 6 based on the free volume theory. Using this modeling coupled with a description of the stress yield changes with Tg, it is possible to predict the long term behavior of thick samples when immersed in sea water. Reliability of the prediction is checked by a comparison with experimental results.
autocad mechanical 2013 crack free 13
... 36 Parks, Forests, and Public Property 2 2013-07-01 2013-07-01 false Loss of status. 222.71 Section 222.71 Parks, Forests, and Public Property FOREST SERVICE, DEPARTMENT OF AGRICULTURE RANGE MANAGEMENT Management of Wild Free-Roaming Horses and Burros 222.71 Loss of status. Wild free-roaming...
In this study the loss of mechanical properties and the interface strength of coated AZ31B magnesium alloy (a magnesium-aluminum alloy) screws with surrounding host tissues were investigated and compared with non-coated AZ31B, degradable polymer and biostable titanium alloy screws in a rabbit animal model after 1, 4, 12 and 21weeks of implantation. The interface strength was evaluated in terms of the extraction torque required to back out the screws. The loss of mechanical properties over time was indicated by one-point bending load loss of the screws after these were extracted at different times. AZ31B samples with a silicon-containing coating had a decreased degradation rate and improved biological properties. The extraction torque of Ti6Al4V, poly-l-lactide (PLLA) and coated AZ31B increased significantly from 1week to 4weeks post-implantation, indicating a rapid osteosynthesis process over 3weeks. The extraction torque of coated AZ31B increased with implantation time, and was higher than that of PLLA after 4weeks of implantation, equalling that of Ti6Al4V at 12weeks and was higher at 21weeks. The bending loads of non-coated AZ31B and PLLA screws degraded sharply after implantation, and that of coated AZ31B degraded more slowly. The biodegradation mechanism, the coating to control the degradation rate and the bioactivity of magnesium alloys influencing the mechanical properties loss over time and bone-implant interface strength are discussed in this study and it is concluded that a suitable degradation rate will result in an improvement in the mechanical performance of magnesium alloys, making them more suitable for clinical application. Copyright 2013 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved. 2ff7e9595c
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